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Part IA Michaelmas Term

Metamerism

Definition

Two light spectra that appear identical despite being physically different are called metamers.

Mathematical Condition

Two spectra L1(λ)L_1(\lambda) and L2(λ)L_2(\lambda) are metamers if:

L1(λ)SL(λ)dλ=L2(λ)SL(λ)dλ\int L_1(\lambda) S_L(\lambda) d\lambda = \int L_2(\lambda) S_L(\lambda) d\lambda

L1(λ)SM(λ)dλ=L2(λ)SM(λ)dλ\int L_1(\lambda) S_M(\lambda) d\lambda = \int L_2(\lambda) S_M(\lambda) d\lambda

L1(λ)SS(λ)dλ=L2(λ)SS(λ)dλ\int L_1(\lambda) S_S(\lambda) d\lambda = \int L_2(\lambda) S_S(\lambda) d\lambda

where SLS_L, SMS_M, SSS_S are the cone sensitivity functions.

Why Metamerism Occurs

Dimension Reduction

  • Visible light spectrum: Infinite dimensions (continuous function)
  • Human cone response: Only 3 values (L, M, S)
  • Information is lost in the transformation

One-Way Mapping

Many different spectra map to the same cone responses:

Spectrumcones(L,M,S)\text{Spectrum} \xrightarrow{\text{cones}} (L, M, S)

The reverse mapping is not unique.

Natural spectrum vs display RGB spectrum producing same perception

Practical Importance

Displays

Displays exploit metamerism:

  • A display emits a narrow RGB spectrum
  • This matches the perception of natural objects with broad spectra
  • The viewer cannot tell the difference

Example: A sunset captured by a camera is reproduced by mixing three narrow-band LEDs. The spectrum is completely different, but the colour matches perceptually.

Colour Reproduction

All colour reproduction relies on metamerism:

  • Printing: CMYK inks spectrum ≠ original reflectance
  • Photography: Sensor spectrum ≠ eye sensitivity
  • Digital displays: RGB primaries ≠ natural light

Conditions for Metamerism

Two spectra are metamers if and only if they have identical tristimulus values:

X1=X2,Y1=Y2,Z1=Z2X_1 = X_2, \quad Y_1 = Y_2, \quad Z_1 = Z_2

Metameric Failure

Metamers may not match under different conditions:

Observer Metamerism

Different observers have slightly different cone sensitivities:

  • Age-related changes (lens yellows)
  • Genetic variation in cone pigments
  • Colour vision deficiency

Illuminant Metamerism

Two surfaces that match under one light may not match under another:

Light SourceSurface ASurface BMatch?
D65 (daylight)Spectrum ASpectrum BYes
A (tungsten)Spectrum ASpectrum BNo

This is critical for:

  • Textile industry (fabrics must match under store lighting)
  • Automotive (interior materials under various light conditions)
  • Printing (proofing under standard illuminant)

Applications

Colour Matching

  • Paint mixing: Find a formulation that matches a target under specified lighting
  • Quality control: Spectral matching vs metameric matching

Colour Science Research

  • Study of observer variation
  • Development of colour difference metrics
  • Design of colour spaces

Summary

  • Metamers are different spectra that produce identical colour perception
  • Occurs because spectrum has infinite dimensions but cone response has only 3
  • Displays rely on metamerism to reproduce colours
  • Metameric matches may fail under different observers or illuminants

Past Paper Questions

2024 Paper 3 Question 3: Explain metamerism. Why is it important for displays?

2023 Paper 3 Question 4: Why can two different spectra appear the same colour?

2022 Paper 3 Question 3: What is illuminant metamerism? Give a practical example.